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Global optimization of Morse clusters by potential energy transformations

Jonathan P. K. Doye, Robert H. Leary, Marco Locatelli and Fabio Schoen

INFORMS Journal on Computing, 16, 371-379 (2004)

Abstract

The Morse potential is a simple model pair potential that has a single parameter rho which determines the width of the potential well and allows a wide variety of materials to be modelled. Morse clusters provide a particularly tough test system for global optimization algorithms, and one that is highly relevant to methods that are to be applied to find the optimal configuration of a biomolecule. In particular, large rho values are very challenging and, until now, no unbiased global optimization method has been able to detect all the (putative) global minima at rho=14 for clusters with up to N=80 atoms. In this paper we introduce some techniques for transforming the original Morse potential that allow us to considerably increase the efficiency in locating the known global minima and also to discover some new optimal clusters. These methods are promising candidates for application to the optimization of biomolecules.


The full paper is available from Optimization Online and INFORMS PubsOnLine.