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Perturbative density functional methods for cholesteric liquid crystalsMaxime M. C. Tortora and Jonathan P.K. DoyeJ. Chem. Phys. 146, 184504 (2017)AbstractWe introduce a comprehensive numerical framework to generically infer the emergent macroscopic properties of uniaxial nematic and cholesteric phases from that of their microscopic constituent mesogens. This approach, based on the full numerical resolution of the Poniewierski-Stecki equations in the weak chirality limit, may expediently handle a wide range of particle models through the use of Monte-Carlo sampling for all virial-type integrals. Its predictions in terms of equilibrium cholesteric structures are found to be in excellent agreement with previous full-functional descriptions, thereby demonstrating the quantitative validity of the perturbative treatment of chirality for pitch lengths as short as a few dozen particle diameters. Furthermore, the use of the full angle-dependent virial coefficients in the Onsager-Parsons-Lee formalism increases its numerical efficiency by several orders of magnitude over that of these previous methods. The comparison of our results with numerical simulations however reveals some shortcomings of the Parsons-Lee approximation for systems of strongly non-convex particles, notwithstanding the accurate inclusion of their full effective molecular volume. Further potential limitations of our theory in terms of phase symmetry assumptions are also examined, and prospective directions for future improvements discussed.The full paper is available from The Journal of Chemical Physics and arXiv.org. |